Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Computed Properties of C10H14O5V, Which mentioned a new discovery about 3153-26-2
The authors report that in soluble metal complex-catalysed autoxidations of car-3-ene, a linear relationship is observed between the oxidation potentials (Eox) of the complexes and their rates of oxidation by car-3-ene-5 hydroperoxide. To the authors’ knowledge, this is the first time a definite relationship has been demonstrated between the redox potentials of catalysts and the rates of hydroperoxide decomposition. The overall oxidation process is considered to consist of several reaction steps. For the complexes presented, certain rate constants are estimated. A number of other complexes fail to show appreciable catalytic activities under the conditions employed (27C, 30 p.s.i. oxygen, carene: catalyst molar ratio = 100:1), or are insoluble (e.g. Co(stearate)2·2H2O) in the solvent (CH3CN) used for the electrochemical measurements.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI