A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, category: catalyst-ligand, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1660-93-1, Name is 3,4,7,8-Tetramethyl-1,10-phenanthroline, molecular formula is C16H16N2. In a Article, authors is Fuge, Felix，once mentioned of 1660-93-1
The palladacycle [Pd(mu-O2CMe){kappa2C,N-4-MeC6H 3N(Me)NO}]2 readily undergoes bridge cleavage reactions with a variety of compounds containing donor functionalities including thioamides, 8-hydroxyquinoline, thioureas, selenoureas, acetylacetone derivatives, dithiocarbamates, xanthates, as well as bidentate N-donors to afford either the monomeric, neutral Pd(II) complexes [Pd{kappa2C,N-4-MeC6H3N(Me)NO}{L-L}] or the monocationic complexes [Pd{kappa2C,N-4-MeC6H3N(Me)NO}(N-N)]P F6 in high yields. A series of 15 different complexes was prepared and fully characterised spectroscopically and, in some cases, by X-ray diffraction. It was also found that the dithiocarbamato complex undergoes a disproportionation reaction in solution to give the bis(cyclometallated) complex [Pd{kappa2C,N-4-MeC6H3N(Me)NO} 2] as well as the bis(dithiocarbamato) complex [Pd{kappa2S-S2CNEt2}2].
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1660-93-1, help many people in the next few years.category: catalyst-ligand
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI