《From 1,2-difunctionalisation to cyanide-transfer cascades – Pd-catalysed cyanosulfenylation of internal (oligo)alkynes》 was written by Buerger, Marcel; Loch, Maximilian N.; Jones, Peter G.; Werz, Daniel B.. Quality Control of Tris(dibenzylideneacetone)dipalladium(0) And the article was included in Chemical Science in 2020. The article conveys some information:
Internal alkynes substituted by aliphatic or aromatic moieties or by heteroatoms were converted into sulfur-substituted acrylonitrile derivatives Key is the use of Pd catalysis, which allows the addition of aromatic and aliphatic thiocyanates in an intra- and intermol. manner. Substrates with several alkyne units underwent further carbopalladation steps after the initial thiopalladation step, thus generating in a cascade-like fashion an oligoene unit with sulfur at one terminus and the cyano group at the other. In addition to this study using Tris(dibenzylideneacetone)dipalladium(0), there are many other studies that have used Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Quality Control of Tris(dibenzylideneacetone)dipalladium(0)) was used in this study.
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors.Quality Control of Tris(dibenzylideneacetone)dipalladium(0)It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI