Quality Control of Tris(dibenzylideneacetone)dipalladium(0)In 2019 ,《Templating Porphyrin Anisotropy via Magnetically Aligned Carbon Nanotubes》 appeared in ChemPlusChem. The author of the article were Dordevic, Luka; Marangoni, Tomas; Liu, Mingjie; De Zorzi, Rita; Geremia, Silvano; Minoia, Andrea; Lazzaroni, Roberto; Ishida, Yasuhiro; Bonifazi, Davide. The article conveys some information:
The preparation and characterization of a novel three-dimensional organic material consisting of porphyrin arrays on carbon nanotubes embedded in an organogel is reported. Firstly, the porphyrin array was prepared through metal-ligand coordination of a ditopic ligand (1,2-bis(4-pyridyl)ethane) and two bis-Zn(II) porphyrins, linked through a pyrene core, and was studied through UV-Vis, NMR and diffusion spectroscopies. Secondly, the porphyrin supramol. architecture was adsorbed on pristine carbon nanotubes, greatly improving the dispersibility of the latter in organic solvents. The hybrid material was characterised by means of UV-Vis spectroscopy, microscopic techniques and thermogravimetric anal. Finally, by exploiting the anisotropic magnetic susceptibility of carbon nanotubes, the hybrid material was aligned under a magnetic field, the organization of which could be maintained by in situ gelation. The resultant hybrid organogel exhibited notable optical anisotropy, suggesting an anisotropic arrangement of the porphyrin-CNTs architectures in the macroscopic material. The experimental process involved the reaction of Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Quality Control of Tris(dibenzylideneacetone)dipalladium(0))
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors.Quality Control of Tris(dibenzylideneacetone)dipalladium(0) It is also used in the synthesis of polymer bulk-heterojunction solar sells as a semiconductor.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI