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On treatment with thallium(III) nitrate, trihydrate in acetonitrile solution, 3,4,6-tri-O-benzyl-D-glucal (5) gives the ring-contracted aldehyde (6) which has been converted into the showdomycin analogue (8) ; 2-(alpha-D-2′-deoxyribofuranosyl)maleimide (12) has similary been prepared from (10) in satisfactory overall yield.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI