Synthetic Route of 16858-01-8, In heterogeneous catalysis, the catalyst is in a different phase from the reactants. At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 16858-01-8, name is Tris(2-pyridylmethyl)amine. In an article,Which mentioned a new discovery about 16858-01-8
A series of trans- and cis-dinuclear squarato-bridged copper(II) complexes [Cu2(dpya)4(mu1,3-C4O4)](ClO4)2·MeOH (1), [Cu2(bdmpzpy)2(mu1,3-C4O4)(H2O)2](ClO4)2·5H2O (2) and [Cu2(pmea)2(mu1,2-C4O4)](ClO4)2·1.5H2O (3) derived from di-, tri- and tetra-dentate pyridyl amine ligands (C4O42- is the 3,4-dihydroxycyclobut-3-en-1,2-dione dianion = squarate dianion, dpya = di-2-pyridylamine, bdmpzpy = 2,6-bis[(2,5-dimethyl-1H-pyrazolyl)methyl]pyridine, pmea = bis(2-pyridylmethyl)-2-(2-pyridylethyl)amine) were synthesized and structurally characterized by single crystal X-ray crystallography. In this series, structures consist of the ClO4- groups as counter ions and the C4O42- is bridging two Cu(II) ions in a mu-1,3-bis(monodentate) (1 and 2) and a mu-1,2-bis(monodentate) (3) bonding modes. The coordination environment around the Cu(II) centers in these complexes is a five-coordinate with a distorted square geometry where the intra-dinuclear Cu…Cu distances across the bridged squarato ligand are in the range 7.26-7.82 A in the trans mu1,3- complexes 1 and 2, and 6.76 A in the corresponding cis mu1,2- complex 3. The magnetic measurements in the 4.5-300 K temperature range reveal weak antiferromagnetic coupling in the three complexes (|J| = 2.4-12.4 cm-1).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.16858-01-8. In my other articles, you can also check out more blogs about 16858-01-8
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI