27-Sep News Some scientific research about 16858-01-8

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Binding of 3,5-di-tert-butyl-1,2-benzochatechol (H2DTBC) at ZnII complexes of a tetradentate, tripodal ligand L is significantly enhanced (36-4.6 × 104 fold), and its reduction potential shifted (90-270 mV) to more positive values by introducing one to three amino hydrogen bond donors. The structure of one of the [(L)Zn(DTBC)] complexes is reported and shows intramolecular N-H…O hydrogen bonding between the ligand-based amino group and the ZnII-bound chatecholate, which provides an explanation for the observed behavior.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI