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A wide variety of 6-aryl-5-phenyl-1,2-dithiafulvenes and 6-aroyl-5-phenyl-1,2-dithiafulvenes (4) have been synthesized by the interaction of 5-phenyl-1,2-dithiol-3-one (3a) and phosphonium ylides (2).The synthesis of these dithiafulvenes has also been carried out by an alternative route involving the condensation of 2 with 5-phenyl-1,2-dithiol-3-thione (3b).The spectral data ara consistent with the proposed structures for the products.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI