In heterogeneous catalysis, the catalyst is in a different phase from the reactants. 16858-01-8. At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 16858-01-8, name is Tris(2-pyridylmethyl)amine. In an article£¬Which mentioned a new discovery about 16858-01-8
Synthesis, characterization, and photoresponsive properties of a series of Mo(iv)-Cu(ii) complexes
Six Mo(iv)-Cu(ii) complexes, [Cu(tpa)]2[Mo(CN) 8]¡¤15H2O (1, tpa = tris(2-pyridylmethyl)amine), [Cu(tren)]2[Mo(CN)8]¡¤5.25H2O (2, tren = tris(2-aminoethyl)amine), [Cu(en)2][Cu0.5(en)][Cu 0.5(en)(H2O)][Mo(CN)8]¡¤4H2O (3, en = ethylenediamine), [Cu(bapa)]3[Mo(CN)8] 1.5¡¤12.5H2O (4, bapa = bis(3-aminopropyl)amine), [Cu(bapen)]2[Mo(CN)8]¡¤4H2O (5, bapen = N,N?-bis(3-aminopropyl)ethylenediamine), and [Cu(pn)2][Cu(pn)] [Mo(CN)8]¡¤3.5H2O (6, pn = 1,3-diaminopropane), were synthesized and characterized. Single-crystal X-ray diffraction analyses show that 1-6 have different structures varying from trinuclear clusters (1-2), a one-dimensional belt (3), two-dimensional grids (4-5), to a three-dimensional structure (6). Magnetic and ESR measurements suggest that 1-6 exhibit thermally reversible photoresponsive properties on UV light irradiation through a Mo(iv)-to-Cu(ii) charge transfer mechanism. A trinuclear compound [Cu(ii)(tpa)]2[MoV(CN)8](ClO4) (7) was synthesized as a model of the photoinduced intermediate. The Royal Society of Chemistry 2011.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 16858-01-8 is helpful to your research. 16858-01-8
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI