A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Safety of (1R,2R)-Cyclohexane-1,2-diamine, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 20439-47-8, Name is (1R,2R)-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a Article, authors is Borovkov, Victor V.£¬once mentioned of 20439-47-8
Stoichiometry-controlled supramolecular chirality induction and inversion in bisporphyrin systems
Chemical equation presented Stoichiometry is found to be an effective tool for controlling supramolecular chirality induction and inversion processes. Chirality induction in the achiral syn ethane-bridged bis(zinc octaethylporphyrin) is achieved upon interaction with the enantiopure (R,R)-1,2-diphenylethylenediamine at the low molar excess region, to yield the right-handed chiral 1:1 tweezer complex. Further increase of the ligand concentration results in chirality inversion as the equilibrium shifts toward the extended left-handed 1:2 anti complex as a result of switching of the complex helicity.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 20439-47-8, help many people in the next few years.Safety of (1R,2R)-Cyclohexane-1,2-diamine
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI