A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Computed Properties of C6H11NO2, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 3105-95-1, Name is H-HoPro-OH, molecular formula is C6H11NO2. In a Article, authors is Zhang, Shi-Jin£¬once mentioned of 3105-95-1
Stereoselective synthesis of (?)-3-PPP through palladium-catalysed unactivated C(sp3)?H arylation at the C-3 position of L-pipecolinic acid
An efficient route for the preparation of (?)-3-PPP(preclamol) using the highly stereoselective palladium-catalysed C(sp3)-H arylation and radical decarboxylation reaction as the key steps is described. The chiral center at the C-3 position of L-pipecolinic acid derivative formed in the key reaction was completely induced by the adjacent stereocenter of the substrate, which was confirmed by the data of chiral HPLC analysis. Substitution effect of nitrogen on the efficiency of Pd-catalysed C(sp3)-H arylation reaction was explored with substantial experiments including the X-ray single-crystal diffraction analysis of palladium-complex-2.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 3105-95-1, help many people in the next few years.Computed Properties of C6H11NO2
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI