In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 112068-01-6, name is (S)-Diphenyl(pyrrolidin-2-yl)methanol, introducing its new discovery. Recommanded Product: (S)-Diphenyl(pyrrolidin-2-yl)methanol
An enantioselective approach to cytotoxic norcalamenenes via electron-transfer-driven benzylic umpolung of an arene tricarbonyl chromium complex
An efficient enantioselective total synthesis of (R)-1-isopropenyl-6-methoxy-7-methyl-1,2,3,4-tetrahydronaphthalene, the dehydro-analog of the cytotoxic norsesquiterpene (R)-7-demethyl-2-methoxycalamenene, was achieved in seven steps starting from 6-methoxytetralone. The synthesis exploits the specific reactivity and stereochemistry of planar chiral eta6-arene-Cr(CO)3 complexes. In a key step, a Cr(CO)3-complexed benzylic anion, regioselectively generated by means of electron- transfer-driven benzylic umpolung, is diastereoselectively alkylated with acetyl chloride.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 112068-01-6 is helpful to your research. Recommanded Product: (S)-Diphenyl(pyrrolidin-2-yl)methanol
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI