Archives for Chemistry Experiments of (R)-[1,1′-Binaphthalene]-2,2′-diamine

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Optical activity in the biaryl series

The relationship between the CD spectra of the chiral biaryls and their stereochemical configuration, as a function of the dihedral angle between the molecular planes of the aromatic moieties, has been investigated for biphenyl, 1,1?-binaphthyl, 1,1?-bianthryl and 9,9?-bianthryl in the exciton approximation and, for the 1,1?-binaphthyls, in the pi-SCF approximation. Both methods provide unambiguous assignments of absolute configuration except for biaryls with a critical dihedral angle of pi/2 in those with effective Ddata2 chromophoric symmetry, or 100-110 in the case of the 1,1?-binaphthyls.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI