Chemistry is traditionally divided into organic and inorganic chemistry. HPLC of Formula: C14H16N2. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 150-61-8
Stereoselective synthesis of hexacoordinated mononuclear cyclometalated rhodium(III) complexes – Transfer of chirality from the metal center to the ligand
The cleavage of DeltaDelta[Rh(th4,5ppy)2(mu-C1)]2 [th4,5ppy is enantiomerically pure (8R,10R)-2-(2?-thienyl)-4,5-pinenopyridine(-)] by 5 different diimines and 11 diamines yields monomeric cations Delta[Rh(th4,5ppy)2(N?N)]+. In all cases, the cleavage reaction preserves the original Delta configuration at the metal center. When N?N is a chiral or a prochiral ligand, various degrees of stereoselectivity is observed, depending on where the stereogenic center is located in N?N. The reported results open up a systematic method towards the synthesis of tris(bidentate)RhIII complexes with a completely predetermined stereochemistry.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C14H16N2, you can also check out more blogs about150-61-8
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI