In an article, author is Wang, Meng, once mentioned the application of 7531-52-4, Computed Properties of C5H10N2O, Name is H-Pro-NH2, molecular formula is C5H10N2O, molecular weight is 114.15, MDL number is MFCD00005253, category is catalyst-ligand. Now introduce a scientific discovery about this category.
A new 3D luminescent Ba-organic framework with high open metal sites: CO2 fixation, luminescence sensing, and dye sorption
A new 3D luminescent Ba-organic framework {[Ba3L2(NMP)(2)(H2O)(2)]center dot 2NMP center dot H2O}(n) (1) was first synthesized based on Ba(II) and a triangular-shaped bridging rigid ligand, namely 1,3,5-tris(4-carboxyphenly)benzene (H3L), via solvothermal reaction (NMP = N-methyl pyrrolidone), thereby forming a stabilized network including a one-dimensional (1D) infinite rod-like helical metal chain. 1 may be explored as a recyclable heterogeneous catalyst for the efficient fixation of CO2 to form serviceable cyclic carbonate since 1D channels remain decorated with abundant open metal sites (OMSs), and the catalytic efficiency of 1 was up to 98% for 1-bromo-2,3-propylene oxide. Simultaneously, the luminescence sensing shows that 1 has excellent response and sensitivity towards pollutants such as Fe3+, Cr2O72-, CrO42-, and [Fe(CN)(6)](3-) ions. Moreover, 1 exhibits the particularly selective sorption towards the Congo red (CR) dye. Consequently, this study may provide a facile synthetic route for the construction of multi-functional Ba-MOF materials.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI