Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 3144-16-9, Name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid, SMILES is O=S(C[C@@]1(C2(C)C)C(C[C@@]2([H])CC1)=O)(O)=O, in an article , author is Urano, Chisato, once mentioned of 3144-16-9, HPLC of Formula: C10H16O4S.
Asymmetric allylic substitution by chiral palladium catalysts: Which is more reactive, major pi-allyl Pd(II) species or minor pi-allyl species?
The reactivity difference of major and minor n-allyl species was examined for two typed asymmetric allylic substitutions via linear symmetrical pi-allyl and linear unsymmetrical pi-allyl intermediates. P-31 NMR observation of the stoichiometric reaction of [Pd(1,3-diphenyl-pi-allyl)(N-P-N-type ligand)](+) with malonate ion verified that major species was much more reactive than the minor one. In the case of the reaction of [Pd(1,1,3-trimethyln-allyl)((S)-BINAP)](+) species with soft amido ion, increase in the minor/major ratio of the n-allyl species afforded higher enantioselectivity to indicate that the minor pi-allyl was more reactive than the major one.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI