Application of 3153-26-2, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3153-26-2, Name is Vanadyl acetylacetonate, molecular formula is C10H14O5V. In a Article，once mentioned of 3153-26-2
Oxidovanadium(V) complexes containing hydrazone based O,N,O-donor ligands: Synthesis, structure, catalytic properties and theoretical calculations
Two new mono oxidovanadium(V) complexes, [VOL1(OEt)] (1) and [VOL2(OMe)] (2), of the tridentate Schiff base hydrazone-type O,N,O-donor ligands H2L1 and H2L2, obtained by monocondensation of 3-hydroxy-2-naphthohydrazide with 5-bromo-2-hydroxybenzaldehyde and benzoylacetone, respectively, have been synthesized starting from VO(acac)2 [H2L1 = (E)-N?-(5-bromo-2-hydroxybenzylidene)-3-hydroxy-2-naphthohydrazide; H 2L2 = (E)-3-hydroxy-N?-((Z)-4-hydroxy-4-phenylbut-3- en-2-ylidene)-2-naphthohydrazide]. Single-crystal X-ray structure analysis revealed for both complexes a slightly distorted square-based pyramidal NO 4 coordination environment around the metal centre, with the aroylhydrazone Schiff bases acting as O,N,O-tridentate, dinegative ligands. The complexes were also characterized by spectroscopic methods in the solid state (IR) and in solution (UV-Vis, 1H NMR) and by cyclic voltammetric experiments in DMSO, and their properties were interpreted by means of DFT theoretical calculations. The catalytic potential of these complexes has been tested for the oxidation of thioanisol using H2O2 as the terminal oxidant. The effects of various parameters, including the molar ratio of oxidant to substrate, the temperature and the solvent, have been studied. Both complexes showed superabundant catalytic activity in the oxidation of thioanisol at room temperature with excellent conversions.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI