New explortion of 2-Methyl-1H-indene

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Palladium-Catalyzed Cyclization of Benzyl Halides and Related Electrophiles Containing Alkenes and Alkynes as a Novel Route to Carbocycles

Treatment of benzyl halides and related electrophiles containing alkene and alkyne groups with a catalytic amount of Pd complexes, such as Pd(PPh3)4, provides the corresponding cyclization products containing five- through seven-membered rings often with retention of the alkene regiochemistry.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI