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We report the first asymmetric synthesis of the individual enantiomers of methylphenidate (1). From d-pipecolic acid, the (2R,2’R) and (2S,2’R) enantiomers of 1 were obtained in >99% optical purity while the (2S,2’S) and (2R,2’S) enantiomers of 1 were derived from l-pipecolic acid in 96% optical purity. The versatility of this methodology is demonstrated with the synthesis of the (2R,2’R) and (2S,2’S) enantiomers of p-bromo and p-methoxy derivatives in similar yields and enantiomeric purities. Comparative neurochemical assessments of these synthesized enantiomers at purported dopamine, norepinephrine, and serotonin uptake sites along with locomotor activity studies in rats are also reported.
Because enzymes can increase reaction rates by enormous factors and tend to be very specific, Recommanded Product: 3105-95-1, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 3105-95-1
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI