Application of 3153-26-2, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3153-26-2, Name is Vanadyl acetylacetonate, molecular formula is C10H14O5V. In a Article,once mentioned of 3153-26-2
The effect of amide coordination on the parallel coupling constant has been determined for three square pyramidal vanadyl complexes. The complexes V(IV)O(PAAP), V(IV)O(PAIS), and [V(V)O(HIBA)][C4H9)4N] have been prepared, and the latter two have been structurally characterized (PAAP is the dianion of 1,2-bis(2-carboxamidopyridyl)benzene, PAIS is the dianionof [N-(salicylideneamine)phenyl]pyridine-2-carboxamide], HIBA is the tetraanion of 1,2-bis(2-hydroxy-2-methylpropanamido)benzene). X-ray diffraction quality crystals of V(IV)O(PAIS) were obtained by slow evaporationof a nitromethane solution of V(IV)O(PAIS). X-ray parameters for V(IV)O(PAIS): C19H13N3O3V1, 382.08 g/mol, P21/n, a = 7.777(3) A, b = 18.433(7) A, c = 11.565(4) A, beta = 102.66(3)°; V = 1633(1)A**3; Z = 4. The final refinement yielded R = 0.0600 and Rw = 0.0450. X-ray diffraction quality crystals of [V(V)O(HIBA)][(C4H9)4N] were obtained by slow evaporation of a THF-CHCl3 solution of [V(V)O(HIBA)][(C4H9)4N]. X-ray parameters for [V(V)O(HIBA)][C4H9)4N]: C30H52N3O5V1, 585.69g/mol, P21/n; a = 13.228(3) A, b = 16.054(4) A, c = 14.7140(20)A, beta = 93.240(10)°; V = 3119.7(11) A**3; Z = 4. Thefinal refinement yielded R = 0.051 and Rw = 0.047. Comparison of calculated and experimental values of A.dblvert. for vanadyl-bleomycin and vanadyl-serum albumin support the presence of a deprotonated amide donor(s)in vanadyl-bleomycin but not in vanadyl-serum albumin.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 3153-26-2 is helpful to your research. Application of 3153-26-2
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI