Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Computed Properties of C7H18ClN, Which mentioned a new discovery about 14251-72-0
The photochlorinations of the n-butyl, n-pentyl, and n-hexyltrimethylammonium chlorides, using molecular chlorine in hexachloroacetone or 15percent CD3CO2D/85percent H2SO4, or using N-chlorodimethylamine in the acid solvent are described.The ammonium group exerted a strong polar directing effect upon the site of substitution.This effect was found to be more pronounced in the more polar protic solvent.The reagent, N-chlorodimethylamine, generated the dimethylamminium radical, whose reaction showed a polar sensitivity toward hydrogen abstraction similar to that of the chlorine atom, but exhibiting a much greater secondary/primary selectivity.Comparison of the isomer distributions obtained from the self photochlorination reactions of N-chloro-n-hexylmethylamine and N-chloro-n-pentylmethylamine in the acid solvent, with the distribution pattern obtained for the chlorinations of the ammonium salts with N-chlorodimethylamine, suggested that the self chlorinations of the N-chloroamines proceed by the intramolecular hydrogen abstraction mechanism suggested previously.
Because enzymes can increase reaction rates by enormous factors and tend to be very specific, Computed Properties of C7H18ClN, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 14251-72-0
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI