1662-01-7, 4,7-Diphenyl-1,10-phenanthroline is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
1662-01-7, General procedure: The formerly reported protocol for the preparation of complex Ru-Cl [1] was modified,as described below, and this modification was used also for the Os(II) analogue Os-Cl. Thestarting dimer [M(mu-Cl)(eta6-pcym)Cl]2 (0.10 mmol; M = Ru or Os) reacted with an excess (0.15mmol) of bphen in 5 mL of MeOH in a microwave reaction system (100 C, 1 min). Theobtained solutions were cooled to ambient temperature, and an excess of NH4PF6 (3.0 mmol)was added. The solvent volume was reduced after 15 min of stirring at ambient temperature,until the solid formed. The obtained chlorido complexes [Ru(eta6-pcym)(bphen)Cl]PF6 (Ru-Cl)and [Os(eta6-pcym)(bphen)Cl]PF6 (Os-Cl) were collected by filtration, washed (1 ¡Á 0.5 mL ofMeOH and 3 ¡Á 1 mL of diethyl ether) and dried under vacuum.
As the paragraph descriping shows that 1662-01-7 is playing an increasingly important role.
Reference£º
Article; Starha, Pavel; Travni?ek, Zden?k; Van?o, Jan; Dvo?ak, Zden?k; Molecules; vol. 23; 2; (2018);,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI