112881-51-3, 4′-(4-Pyridyl)-2,2′:6′,2”-terpyridine is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: Ru(1)Cl3 (0.10 g, 0.17 mmol) and ligand 3 (0.05 g, 0.17 mmol) was suspended in ethane-1,2-diol (8 cm3). The suspension heated at 150 C for 2 h. The deep red solution was poured into excess aqueous KPF6 (20 mL). A red precipitate formed and was collected on Celite, washed with H2O (5 mL), EtOH (2 mL), Et2O (5 mL), and dissolved in CH3CN. The product was purified by chromatography (SiO2, CH3CN:H2O:saturated aqueous KNO3 14:1.2:0.5). Addition of excess aqueous saturated KPF6 solution and removal of CH3CN under reduced pressure gave a red precipitate which was collected on Celite, washed with H2O (5 mL), EtOH (2 mL), Et2O (5 mL) and dissolved in CH3CN. Removal of solvent gave [Ru(1)(3)](PF6)2 as a red solid (74 mg, 68 mumol, 40%)., 112881-51-3
As the paragraph descriping shows that 112881-51-3 is playing an increasingly important role.
Reference£º
Article; Shen, Chao; Wang, Pi; Beves, Jonathon E.; Polyhedron; vol. 103; (2016); p. 241 – 247;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI