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Inflatable rings: Low-valent Ni0-nitrogen-heterocyclic carbene catalysts were found to isomerize activated and unactivated vinyl cyclopropanes to their respective substituted cyclopentenes under mild conditions and in high yields (see scheme, cod = cycloocta-1,5-diene).

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI