Electric Literature of 4062-60-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.4062-60-6, Name is N1,N2-Di-tert-butylethane-1,2-diamine, molecular formula is C10H24N2. In a Conference Paper，once mentioned of 4062-60-6
A series of 5-hexenyllithiums having a phenyl, trimethylsilyl, or cyclopropyl substituent at the terminal [C(6)] alkene carbon have been prepared from the corresponding iodides by lithium-iodine exchange with t-butyllithium at -78C. Although 6-alkyl-substituted 5-hexenyllithiums do not isomerize to five-membered rings upon warning, terminally substituted 5-hexenyllithiums bearing a moderately activating phenyl or trimethylsilyl group cleanly undergo a totally regiospecific 5-exo cyclization at sub-ambient temperatures to afford five membered rings bearing a CHRLi moiety that may be trapped with an electrophile to deliver high yields of functionalized product. Cyclization of 6-cyclopropyl-5-hexenyllithium is accompanied by ring opening of the three-membered ring.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI