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New oxidovanadium(V) complexes, [VOL1(bzh))]·H2O (1) and [VOL2(bzh))] (2), were prepared by the reaction of [VO(acac)2] (where acac = acetylacetonate) and benzohydroxamic acid (Hbzh) with N?-(5-bromo-2-hydroxybenzylidene)-3-methylbenzohydrazide (H2L1) and N?-(5-bromo-2-hydroxybenzylidene)- 4-methylbenzohydrazide (H2L2), respectively, in methanol. Structures of the complexes were determined by elemental analysis, infrared and UV?vis spectra. Single crystal structures of the complexes were determined by X-ray diffraction. Vanadiums have octahedral coordination. Thermal stability and the inhibition of urease of the complexes were studied.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI