1662-01-7, 4,7-Diphenyl-1,10-phenanthroline is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: Preparation of the [Ir(C^N)2(N^N)]3+[PF6-]3: in typical reaction procedure 0.10 g (0.058 mmol) of [{Ir(C^N)2Cl}2]4+[PF6]4, 0.04 g (0.16 mmol) AgPF6 and 0.03-0.06 g (0.19 mmol) of N^N ligand were heated at 100 C under argon in 15 ml of argon-purged 2-methoxyethanol/water mixture (8:2 v/v) for ca. 36 h. After cooling, the reaction mixture to ambient temperature, the precipitated AgCl was filtered off and the solvents were removed by rotary evaporation. The residue was dissolved in small amount of acetone and an excess of [NnBu4]Cl was added. The precipitate was filtered off and washed with acetone. The hexafluorophosphate salts were further obtained by anion metathesis with NH4PF6 in cold water with yields: [Ir(C^N)2(phen)]3+[PF6-]3 64%, [Ir(C^N)2(tmphen)]3+[PF6-]3 81%, [Ir(C^N)2(dpphen)]3+[PF6-]3 53%, [Ir(C^N)2(dpq)]3+[PF6-]3 42%, [Ir(C^N)2(dppz)]3+[PF6-]3 39%, [Ir(C^N)2(dppn)]3+[PF6-]3 57%. For the NMR data see Supporting information.
1662-01-7, The synthetic route of 1662-01-7 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Kamecka, Anna; Grochowska, Olga; Kapturkiewicz, Andrzej; Inorganic Chemistry Communications; vol. 108; (2019);,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI