Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 89972-77-0, is researched, SMILESS is CC1=CC=C(C2=CC(C3=NC=CC=C3)=NC(C4=NC=CC=C4)=C2)C=C1, Molecular C22H17N3Journal, Crystal Growth & Design called Unusual 2D → 3D Polycatenane Frameworks Based on 1D → 2D Interdigitated Layers: From Single Crystals to Submicrometer Fibers with Enhanced UV Photocatalytic Degradation Performances, Author is Guo, Jiao; Ma, Jian-Fang; Li, Jun-Jie; Yang, Jin; Xing, Shuang-Xi, the main research direction is crystal structure cobalt manganese zinc cadmium tolylterpyridine tetracarboxylate; transition metal terpyridine carboxylate MOF preparation photocatalytic activity; methylene blue photocatalytic degradation catalyzed transition metal tolylterpyridine tetracarboxylate.HPLC of Formula: 89972-77-0.
Four unusual isomorphous metal-organic frameworks, [M2(L1)(L2)2] (M = Co for 1, Mn for 2, Zn for 3, and Cd for 4), where H4L1 = tetrakis[4-(carboxyphenyl)-oxamethyl]methane acid and L2 = 4-tolyl-2,2′:6′,2”-terpyridine, were synthesized under hydrothermal conditions. Their structures were determined by single-crystal x-ray diffraction analyses and further characterized by IR spectra, elemental analyses, powder X-ray diffraction, UV-visible absorption spectra, and optical energy gaps. In 1-4, the metal atoms are linked by the L1 anions to yield a chain with a loop. Every loop of each chain is penetrated by two L2 ligand rods from the two nearest chains, resulting in an unusual 1-dimensional → 2-dimensional interdigitated network. In the 2-dimensional interdigitated network, there exist weak π-π interactions between pyridyl groups of L2 ligands. If the π-π interactions are regarded as linkers, the 2-dimensional interdigitated network belongs to an uneven (3,4)-connected layer. Also, each individual (3,4)-connected layer is polycatenated with an infinite number of other perpendicular layers, yielding an unusual 2-dimensional → 3-dimensional polycatenane framework. The luminescent properties of compounds 3 and 4 were studied. Compounds 1-4 exhibit photocatalytic activities for MB degradation under UV irradiation Submicrometer fiber 1′ shows high photocatalytic efficiency for MB degradation with respect to its corresponding macroscaled crystalline 1.
In addition to the literature in the link below, there is a lot of literature about this compound(4-(p-Tolyl)-2,2:6,2-terpyridine)HPLC of Formula: 89972-77-0, illustrating the importance and wide applicability of this compound(89972-77-0).
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI