The author of 《Palladium/XuPhos-Catalyzed Enantioselective Carboiodination of Olefin-Tethered Aryl Iodides》 were Zhang, Zhan-Ming; Xu, Bing; Wu, Lizuo; Zhou, Lujia; Ji, Danting; Liu, Yu; Li, Zhiming; Zhang, Junliang. And the article was published in Journal of the American Chemical Society in 2019. Application of 51364-51-3 The author mentioned the following in the article:
A highly enantioselective palladium-catalyzed iodine atom transfer cycloisomerization of unactivated alkenes was developed. This represents the first example of highly enantioselective carboiodination of olefin-tethered aryl iodides, which provides a perfect atom economy method to construct a series of optically active 2,3-dihydrobenzofuran, indolines and chromane bearing an alkyl iodide group in moderate to good yields. Moreover, the use of readily available starting materials, a broad substrate scope, high selectivity, mild reaction conditions, as well as versatile transformation of the product make this approach attractive. The mechanism of this Pd(0)-catalyzed asym. carboiodination of alkenes was studied with d. functional theory. In the experiment, the researchers used many compounds, for example, Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Application of 51364-51-3)
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors.Application of 51364-51-3It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI