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Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, the author is Blake, Paul C. and a compound is mentioned, 1271-19-8, Titanocenedichloride, introducing its new discovery. 1271-19-8
Bis(trimethylsilyl)phosphido complexes II. Bis(trimethylsilyl)phosphidobis(tetrahydrofuran)lithium as a reducing agent; X-ray structure of
The lithium compound (THF)2>2 (I) in tetrahydrofuran (THF) under ambient conditions is an effective reducing agent for converting cyclopentadienyl-titanium(IV) or -uranium(IV) chlorides into the corresponding chlorocyclopentadienylmetal(III) complexes.Thus , , and were transformed in high yields into , , and (II), respectively.The crystalline complex II is triclinic, space group P1<*>, with a 11.352(5), b 12.795(7), c 15.o14(7) Angstroem; alpha 101.63(7), beta 90.34(4), gamma 95.92(6) deg, and Z = 2.Its X-ray structure was refined to R1 = 0.056 and R2 = 0.072.The compound is a monomer, with mean U-Cl and Li-Cl bond lengths of 2.730(1) and 2.46(6) Angstroem, respectively; and Cl-U-Cl’, Cl-Li-Cl’, and U-Cl-Li 82.3(2), 94(2), and 91(1) deg, respectively.
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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI