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Self- and directed assembly of hexaruthenium macrocycles
Rigid terpyridine-based building blocks allow easy access to large polymetallomacrocycles (see picture) through a self-assembly process. Such routes are envisioned to provide one-step methods to higher order motifs and facilitate the creation of precisely organized, metal-based networks for new energy storage devices.
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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI