29176-55-4, 2,9-Dichloro-1,10-phenanthroline is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
Preparation of E-l-(6-methyl-pyridin-2-yl)-ethanone-O-r3-(9-chloro-rif101phenanthrolin- 2-yl)-prop-2-ynyl1-oxime2,9-Dichloro-[l,10]phenanthroline (0.46 g) and E-l-(6-methyl-pyridin-2-yl)-ethanone-0- prop-2-ynyl-oxime (382 mg) were dissolved in THF (5 ml_). Diisopropylamine (1.88 g), dichlorobis (triphenylphospine)palladium(II) (57 mg) and copper(I) iodide (58 mg) were added. After stirring for 3h at 55C the reaction mixture was poured into water, extracted with ethyl acetate and washed with brine. The organic phase was dried over sodium sulfate, concentrated and purified by chromatography over silica to give l-(6-Methyl-pyridin-2-yl ethanone-O-[3-(9-chloro-[l,10]phenanthrolin-2-yl)-prop-2-ynyl]-oxime as a brown solid., 29176-55-4
The synthetic route of 29176-55-4 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; SYNGENTA PARTICIPATIONS AG; TRAH, Stephan; ZAMBACH, Werner; STIERLI, Daniel; NEBEL, Kurt; BORTOLATO, Andrea; WO2012/62844; (2012); A1;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI