The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 4-(p-Tolyl)-2,2:6,2-terpyridine( cas:89972-77-0 ) is researched.HPLC of Formula: 89972-77-0.Zhou, Xiao-Ping; Ni, Wen-Xiu; Zhan, Shun-Ze; Ni, Jia; Li, Dan; Yin, Ye-Gao published the article 《From Encapsulation to Polypseudorotaxane: Unusual Anion Networks Driven by Predesigned Metal Bis(terpyridine) Complex Cations》 about this compound( cas:89972-77-0 ) in Inorganic Chemistry. Keywords: transition metal terpyridine copper cyano thiocyanato polymeric complex preparation; crystal structure transition metal terpyridine copper cyano thiocyanato polymeric; pseudorotaxane transition metal terpyridine copper cyano thiocyanato polymeric. Let’s learn more about this compound (cas:89972-77-0).
Solvothermal reactions of CuSCN, metal (Mn2+, Fe2+, Co2+, Ni2+, Cu2+) sulfate, and terpyridine (tpy) (2,2′:6′,2”-terpyridine or 4′-p-tolyl-2,2′:6′,2”-terpyridine) in the presence of PPh3 yielded hybrid coordination compounds [Cu6(CN)6(SCN)2·M(tpy)2]m and [Cu6(CN)8·M(tpy)2]m, in which in situ formed metal bis(terpyridine) complex cations are encapsulated by a 3-dimensional anionic network or entangled by 2-dimensional heart-like networks, forming encapsulation or polypseudorotaxane supramols. The complex cations play a role as template to direct the fabrication of the structures.
This compound(4-(p-Tolyl)-2,2:6,2-terpyridine)HPLC of Formula: 89972-77-0 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI