Archives for Chemistry Experiments of 6-Bromo-2,2′-bipyridine

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Synthesis of all-syn functionalized triphenylene ketals

The stereoselective synthesis of triphenylene ketals offers access to unique scaffolds. For a good performance in supramolecular applications an all-syn orientation of the functional groups is essential. The oxidative trimerization of catechol ketals by molybdenum pentachloride or mixtures with titanium tetrachloride leads to a template-directed formation. Several heterocyclic moieties are suitable for this transformation. A template-directed isomerization of anti,anti,syn isomers to the desired C3-symmetric derivative was demonstrated in two cases. Copyright

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 6-Bromo-2,2′-bipyridine, you can also check out more blogs about10495-73-5

Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI