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The coordination behaviour of ligands containing the vitamin B6 vitamers [pyridoxal (PL), pyridoxine (PN), pyridoxamine (PM) and their 5′-phosphates] is reviewed in the light of the structural information derived from X-ray studies. The review includes the complexes of the simple vitamers themselves or simple derivatives thereof; those of the Schiff bases resulting from their condensation with each other or with amino acids or other amino derivatives; and the metal compounds formed by hydrazones that contain the PL moiety. Taken together, these ligands exhibit a wide variety of coordination possibilities, the vitamer moiety usually playing a significant role. The biological relevance and therapeutic potential of some of these compounds are also reviewed.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI