Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， SDS of cas: 1271-19-8, Which mentioned a new discovery about 1271-19-8
Bis(eta 5-cyclopentadienyl)bis(tertio-butanethiolato)titanium(IV) (1) and zirconium(IV) (2) were synthesized with a view to use them as single-source precursors for the preparation of thin films of titanium and zirconium sulfides by the technique of chemical vapour deposition from metal-organic complexes (MOCVD). The crystal and molecular structures have been determined in order to compare them with those of homologous complexes of general formula (eta5-C5H5)2M(SR)2. Both compounds are isostructural [monoclinic, sp. gr. C2/c; a = 16.450(6), b = 9.279(3), c = 12.707(4) A, beta = 108.27(4) for 1; a = 16.604(8), b = 9.384(2), c = 12.884(6)A, beta = 107.86(2) for 2]. The structures are discussed according to the electron configuration of the cation and the bulkiness of the R substituant. CVD experiments were run using (1) or bis(eta5-cyclopentadienyl)bis(ethanethiolato)titanium(IV) (3) as single-source precursors, to grow titanium sulfide thin films. Films with S/Ti < 1 or S/Ti = 1, 1.3 and 1.5 have been obtained depending on the experimental conditions. CVD from (2) gave films with low to very low sulfur contents. Gauthier-Villars. I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1271-19-8, help many people in the next few years.SDS of cas: 1271-19-8
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI