Chemistry is traditionally divided into organic and inorganic chemistry. SDS of cas: 29841-69-8. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 29841-69-8
(Figure Presented) A family of chiral cyclic oxamides was prepared by the condensation of optically active 1,2-diamines with diethyl oxalate. Thionation of the products with Lawesson’s reagent afforded a series of chiral 2,3-piperazinedithiones. Molecular geometries of the title compounds were studied with the use of quantum mechanical DFT calculations and were compared to the X-ray crystallographic results. The heterocyclic six-membered ring adopted a half-chair conformation with the C-5 substituent preferably at the equatorial position, whereas a substitution at the nitrogen atoms resulted in domination of the axial form in the conformational equilibrium. The opposite helicity of the twisted oxamide chromophore in the axial and equatorial conformers led to the opposite signs of the Cotton effects corresponding to two pi-pi* electronic transitions. The CD signs can be predicted by a simple helicity rule. The same rule is valid for 2,3-piperazinodithiones, where a substitution of sulfur for oxygen in the carbonyl groups results in bathochromic shifts of the absorption and CD bands. The crystal packing analysis of several 2,3-piperazinodiones revealed that strong NH…O=C intermolecular hydrogen-bonding interactions generating the chain motif resulted in the formation of 3-D networks as well as with the use of the cyclic hydrogen-bond motif tape structures.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.SDS of cas: 29841-69-8, you can also check out more blogs about29841-69-8
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI