Reference of 96556-05-7, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 96556-05-7, Name is 1,4,7-Trimethyl-1,4,7-triazonane, SMILES is C1CN(CCN(CCN1C)C)C, belongs to catalyst-ligand compound. In a article, author is Shaghaghi, Zohreh, introduce new discover of the category.
Water oxidation activity of azo-azomethine-based Ni (II), Co (II), and Cu (II) complexes
Nickel, cobalt, and copper complexes were synthesized by the reaction of metal acetate salts and azo-azomethine-type ligand H2L (H2L = 4-chloro-1,2-bis[2-hydroxy-5-(phenylazo)benzylideneamino]benzene). The complexes were characterized by spectroscopic methods, molar conductivity measurements, and elemental analysis. The complexes were investigated as water oxidizing catalysts by several electrochemical techniques. Our findings revealed that the nature of the central metal ion plays an essential role in the stability of the complexes and their electrocatalytic activity. Although all modified electrodes with complexes showed good activities for water oxidation compared with bare carbon paste electrode, nevertheless, NiL showed a much superior electrocatalytic activity in basic solution in terms of onset potential and Tafel slope. Experiments indicated that at pH = 11, NiOx is probably a heterogeneous catalyst for the oxidizing of water in the presence of NiL. However, about CoL, it was revealed that a high valent cobalt oxo intermediate is active in the electrocatalytic process. On the other hand, field-emission scanning electron microscope images showed the formation of nanorods on the electrode surface. However, upon our observations, it was difficult to determine the real role of CoL in the water oxidation reaction. Surprisingly, the results indicated that CuL is not stable under electrochemical conditions, and after performing the amperometry for a long time, its electrocatalytic activity decreases.
Reference of 96556-05-7, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 96556-05-7 is helpful to your research.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI