A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, SDS of cas: 1271-19-8, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1271-19-8, Name is Titanocenedichloride, molecular formula is C10Cl2Ti. In a Article, authors is Murr, Nabil El£¬once mentioned of 1271-19-8
ELECTROCHEMICAL BEHAVIOUR OF TITANOCENE DIHALIDES UNDER CO PRESSURE, ELECTROGENERATION OF TITANOCENE CARBONYL DIHALIDE ANIONS AND TITANOCENE DICARBONYL
Cyclic voltammetry of Cp2TiX2 (X=Cl and Br) in THF under CO pressure shows that a chemical reaction with CO accompanies the addition of the first electron to the titanocene dihalides.Electrolysis gave, after the transfer of one electron and a decrease of CO pressure, solutions which exhibited two ESR signals.Electrolysis of these solutions at -1.8 V gave Cp2Ti(CO)2 in high yield after the transfer of a second electron and the absorption of CO.A scheme involving the generation of anions such as (Cp2Ti(CO)X2)- is suggested to explain the results.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1271-19-8, help many people in the next few years.SDS of cas: 1271-19-8
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI