Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.In a patent， Computed Properties of C30H20O8, Which mentioned a new discovery about 1351279-73-6
Due to serious environmental pollutions, the detection of hazardous and explosive nitro-aromatic compounds using metal-organic frameworks (MOFs) have been a promising research field in the current scenario. Here, we report a new fluorescent MOF, [Zn2(TCPE)(tta)2]·2DMF·4H2O·2Me2NH2 + (HNU-34, H4TCPE = 1,1,2,2-tetra(4-carboxylphenyl)ethylene, 1H-tta = 1H-tetrazole) which possesses a 3D configuration and 1D channels along the c-axis. It can serve as a luminescence sensor for the detection of nitrophenol explosives through different quenching effects, especially for the mononitrophenol and dinitrophenol. The detection limits of 2,6-dinitrophenol and trinitrophenol are 29.45 nM and 36.15 nM, respectively, which are among the high level of the reported MOF sensors, especially for DNP.
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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI