Awesome Chemistry Experiments For 1660-93-1

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Chemistry is traditionally divided into organic and inorganic chemistry. SDS of cas: 1660-93-1. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 1660-93-1

Two series of cationic heteroleptic osmium(ii) complexes with a coordinated CO molecule, a chloride Cl- or hydride H- anion, two monodentate triphenylphosphine (tpp) ligands and one bidentate alpha-dimine (N?N) ligand were prepared from an OsCl2(CO)2(tpp)2 precursor. The investigated complexes, available in the form of PF6- salts, have been identified by means of FT-IR, 1H and 31P NMR spectroscopy and X-ray diffraction studies. Their photophysical properties have been investigated in dichloromethane solutions at room temperature and 1:1 ethanol-methanol matrices at 77 K. The investigated complexes exhibit metal to ligand charge-transfer (MLCT) phosphorescence with the emission characteristics distinctly affected by the nature of coordinated alpha-diimine N?N and Cl- or H- ligands. Franck-Condon emission spectral band shape analyses and DFT/TD-DFT calculations have been applied to obtain more detailed insight into the nature of emissive 3?[Os(H)(CO)(N?N)(tpp)2]+ and 3?[Os(Cl)(CO)(N?N)(tpp)2]+ species.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI