Awesome Chemistry Experiments For (1R,2R)-Cyclohexane-1,2-diamine

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A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, name: (1R,2R)-Cyclohexane-1,2-diamine, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 20439-47-8, Name is (1R,2R)-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a Article, authors is Akine, Shigehisa，once mentioned of 20439-47-8

Spontaneous enrichment of one-handed helices by dissolution of quasiracemic crystals of a tetranuclear single helical complex

The left-handed isomer of the helical complex [LZn3La(OAc) 3] was spontaneously enriched from 50:50 to 87:13 when the quasiracemate crystals were dissolved. The invertible helicity of [LZn 3La(OAc)3] (global chirality) helps the quasiracemate formation and the fixed point chirality of the R,R-cyclohexanediamine moiety (local chirality) effectively controls the global chirality in solution. The Royal Society of Chemistry.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI