Awesome Chemistry Experiments For (1S,2S)-(-)-1,2-Diphenylethylenediamine

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Axial chirality is generated upon complexation of the novel triphos ligand with a metal. In the presence of the diamine dm-dabn, isomerization to the enantiopure triphos-Ru complex was observed. The dm-dabn ligand of the Ru complex exchanges with dpen at room temperature without racemization. dm-dabn = 3,3?-dimethyl-2,2?-diamino-1,1?-binaphthyl, dpen = 1,2-diphenylethylenediamine.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI