Reference of 3144-16-9, Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 3144-16-9, Name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid, SMILES is O=S(C[C@@]1(C2(C)C)C(C[C@@]2([H])CC1)=O)(O)=O, belongs to catalyst-ligand compound. In a article, author is Kumari, Sheela, introduce new discover of the category.
Role of substituents present in bidentate ligand frame of Cu(I) catalysts on Sonogashira cross coupling reactions
Cu(I) catalysts {[Cu(L1-4)Cl(PPh3)] where L1-4 = condensed product of 2-(1-phenylhydrazinyl)-pyridine with different benzaldehydes} were synthesized and characterized by H-1 NMR, P-31 NMR, UV-Vis and IR techniques. Complex 2 structure was authenticated by single crystal X-ray method. Different electron donating and withdrawing substituents are present in the ligand frame of Cu(I) catalysts and their role on Sonogashira reaction was investigated. The efficiency order of catalysts for the coupling reaction was found to be 2 > 1 > 3 > 4, clearly indicated the role of substituents present in the ligand frame was useful to effectively catalyze the Sonogashira reaction. The products were characterized using H-1 NMR and C-13 NMR. (C) 2020 Elsevier B.V. All rights reserved.
Reference of 3144-16-9, One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 3144-16-9.
Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI