Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: (R)-[1,1′-Binaphthalene]-2,2′-diol. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 18531-94-7
ON THE MECHANISM OF THE FORMATION OF S(-)-(1.1′-BINAPHTALENE)-2,2′-DIOL VIA COPPER(II)AMINE COMPLEXES
The oxidative dimerization of 2-naphtol is studied by means with several copper(II)amine complexes as oxidants.Using primary amines a chemical yield of 95percent-98percent is obtained.Using (+)-amphetamine as complexing amine a 94percent-96percent optically pure product is obtained.It is established that htis stereoselectivity is a result of selective precipitation of the copper(II)-(+)-amphetamine-(-)-binaphtol complex with a simultaneous racemization of the (+)-binaphtol.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: (R)-[1,1′-Binaphthalene]-2,2′-diol, you can also check out more blogs about18531-94-7
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI