Awesome Chemistry Experiments For (S)-[1,1′-Binaphthalene]-2,2′-diol

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The intramolecular Ullmann coupling of the title diester proceeded in low yield but with virtually complete asymmetric induction in joining the two naphthyl units leading to the 12-membered cyclic diester of (S,S)-configuration, which is the same diastereoisomer obtained from the reaction of (S)-2,2′-bis(1-bromo-2-naphthoyloxy)-1,1′-binaphthyl.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI