Electric Literature of 1271-19-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1271-19-8, Name is Titanocenedichloride, molecular formula is C10Cl2Ti. In a Article£¬once mentioned of 1271-19-8
Reactions of the dinuclear ruthenium complex {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4, featuring a doubly linked dicyclopentadienyl ligand
The complex {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4 (1), which features the doubly linked dicyclopentadienyl ligand (eta5-C5H3)2(SiMe2) 2, reacts with phosphines (PMe3, PCy3, PPh3) to give {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)(mu-CO)2(PR3) (2a-c), with halogens X2 (X = Cl, Br, I) to give the Ru-Ru-cleaved products {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4(X)2 (3a-c), with X2 and AgTfO to give [{(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4(mu-X)]+TfO- (X = Cl, Br, I; 4a-c), and with SnCl2 to give {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4(mu-SnCl2) (5), resulting from the insertion of SnCl2 into the Ru-Ru bond. Reduction of 1 with Na/Hg generates [{(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4]2- (6), which reacts with (eta5-C5H5)2TiCl2 to give {(eta5-C5H3)2(SiMe2) 2}Ru2(CO)4{mu-Ti(eta5-C5 H5)2} (7). Ultraviolet photolysis of 1 with diphenylacetylene and phenylacetylene yields a series of five dinuclear Ru complexes (8-10, 12, 13) containing one or two bridging acetylene units. The rigidity of the doubly linked (eta5-C5H3)2(SiMe2) 2 ligand substantially influences the reactivity and structures of the complexes. Molecular structures of 1, 2a, 3c, 5, 9, 10, and 12 as determined by X-ray diffraction studies are also presented.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 1271-19-8 is helpful to your research. Electric Literature of 1271-19-8
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI