168646-54-6, 5,6-Diamino-1,10-phenanthroline is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
The reaction and workup steps were performed air-free using standard Schlenk technique or by carrying out manipulations in a N2-filled glovebox. Compound 46 (43 mg, 0.2045 mmol, 1 eq) and Re(CO)5Cl (74 mg, 0.2045 mmol, 1 eq) were suspended in 30 rriL of toluene. The mixture was refluxed for 18 h and then cooled to RT followed by further cooling in an 8 ¡ãC fridge for 30 min. The precipitate was isolated via filtration and washed with hexane to obtain analytically pure product in 88percent yield. 1H-NMR (400 MHz, DMSO-d6) delta (ppm): 9.07 (dd, 2H), 8.90 (dd, 2H), 7.91 (dd, 2H), 5.82(s, 4H). 13C-NMR(150.9 MHz, DMSO-d6) 5 (ppm): 198.15, 190.39, 148.49, 140.17, 132.02, 124.81, 123.90, 123.57. ATR-IR(cm_1): 3460(w), 3412(w), 3363(w), 3298(w), 2020(s), 1930(s), 1895(s), 1664(m), 1617(m), 1589(m), 1489(m), 1436(m) Anal. Calcd for Ci5H10N4O3ReCl: C, 34.92; H, 1.95; N, 10.86. Found: C, 35.05; H, 1.82; N, 10.25.
168646-54-6 5,6-Diamino-1,10-phenanthroline 10910805, acatalyst-ligand compound, is more and more widely used in various.
Reference£º
Patent; MASSACHUSETTS INSTITUTE OF TECHNOLOGY; SURENDRANATH, Yogesh; FUKUSHIMA, Tomohiro; O’REILLY, Matthew, E.; OH, Seokjoon; MURRAY, Alexander T.; KAMINSKY, Corey Jarin; CHU, Sterling Ben; JACKSON, Megan N.; (161 pag.)WO2017/31050; (2017); A1;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI