Synthetic Route of 18531-99-2, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 18531-99-2, Name is (S)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a Article,once mentioned of 18531-99-2
A new method for optical resolution of racemic 1,1?-bi-2-naphthol (BINOL) has been developed through molecular complexation with a cheap and readily accessible (S)-5-oxopyrrolidine-2-carboxanilide, affording the enantioenriched BINOL in up to 70.4% ee and 73.6% yield. X-Ray structural analysis of a molecular crystal formed between (R)-BINOL and (S)-5-oxopyrrolidine-2-carboxanilide indicates that the hydrogen bonding interactions between the carbonyl groups of amides and the hydroxyl groups of (R)-BINOL predominate in the molecular complex formation. The chiral features of the amide and the complementary molecular packing in the crystal lattice control the stereochemistry of the guest in the molecular crystal.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Synthetic Route of 18531-99-2, you can also check out more blogs about18531-99-2
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI