Brief introduction of 23364-44-5

Because enzymes can increase reaction rates by enormous factors and tend to be very specific, category: catalyst-ligand, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 23364-44-5

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Asymmetric Synthesis of (1R,2S)-2-Fluorocyclopropylamine, the Key Intermediate of the New Generation of Quinolonecarboxylic Acid, DU-6859

The title synthesis was achieved by featuring diastereoface selective cyclopropanation of (4R,5S)-4,5-diphenyl-3-vinyl-2-oxazolidinone, the chiral and conformationally rigid N-vinylcarbamate, with zincmonofluorocarbenoid followed by hydrogenolysis of formed (4R,5S)-3-<(1R,2S)-2-fluorocyclopropyl>-4,5-diphenyl-2-oxazolidinone. – Key Words: asymmetric synthesis; quinolonecarboxylic acid; (1R,2S)-2-fluorocyclopropylamine; (4R,5S)-4,5-diphenyl-3-vinyl-2-oxazolidinone.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI